Zinc sulfide (ZnS) is a unique compound that forms two types of crystalline structures. Therefore, four sulfur atoms surround each zinc atom and four zinc atoms surround each sulfur atom.2 The coordination number, the number of of electron pairs donated to a metal by its ligands, for both zinc an sulfur is four.1,2 The difference between wurtzite and zincblende lies in the different arrangements of layers of ions.2. Zinc Sulphide is produced by synthesis from Zinc vapour and H 2 S gas, forming as sheets on Graphite susceptors. with zinc sulfide. Since the number of atoms in a single unit cell of Zn and S is the same, it is consistent with the formula ZnS. ESPI Metals. 1. Zinc sulfide – an inorganic compound with the chemical formula ZnS – is a highly purified additive that can be used to enhance coatings and plastics products. 77205. 7446-19-7. Zinc sulfate monohydrate. Solutions of sulfide salts are corrosive. [ "article:topic", "showtoc:no", "sphalerite", "zinc blend structure", "cubic closet packing", "ccp" ], https://chem.libretexts.org/@app/auth/2/login?returnto=https%3A%2F%2Fchem.libretexts.org%2FBookshelves%2FInorganic_Chemistry%2FMap%253A_Inorganic_Chemistry_(Housecroft)%2F06%253A_Structures_and_energetics_of_metallic_and_ionic_solids%2F6.11%253A_Ionic_Lattices%2F6.11E%253A_Structure_-_Zinc_Blende_(ZnS), Calculating density of a crystal structure, information contact us at info@libretexts.org, status page at https://status.libretexts.org. Zinc sulfide is transparent and white in color. Molar mass of ZnS = 97.445 g/mol. Compare Products: Select up to 4 products. Description Zinc sulfide is an inorganic compound with the chemical formula ZnS. 2. Zinc Sulfide occurs naturally as "blend," and is prepared directly from the elements and by precipitation of a zinc salt solution with ammonium sulfide. MDL number MFCD00011301. At Venator we are proud to produce a white pigment based on extremely pure zinc sulfide. 11129-14-9. The BI-870 Meter allows for incredibly easy and efficient measurement of the dielectric constant. Oz. CADMIUM SULFIDE mixed with ZINC SULFIDE (1:1) Cadmium sulfide, mixt. The most common form includes water of crystallization as the heptahydrate, with the formula Zn SO 4 •7H 2 O. Search results for zinc sulphide at Sigma-Aldrich. *Please select more than one item to compare (Author: Maghémite Date: May 5, 2008. Have questions or comments? A representation of ccp structure. Unless otherwise noted, LibreTexts content is licensed by CC BY-NC-SA 3.0. EINECS 269-773-1. By continuing to browse this site you agree to our use of cookies. EINECS 235-672-6. FDA pregnancy category C. It is not known whether zinc sulfate will harm an unborn baby. (2 Pack) $28.50. Zinc and sulfur react with each other violently to produce zinc sulfide; the reaction is accompanied by a vigorous evolution of gas, heat, and light: It is produced at a relatively low cost so many of its applications are as a substitute for other materials. Wurtzite has a hexagonal closest packing structure (hcp), which is characterized by 12 ions in the corners of each unit that create a hexagonal prism (seen in Fig. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite. Before using zinc sulfate, talk to your doctor, pharmacist, or other healthcare provider. ZnS can have a zinc blende structure which is a "diamond-type network" and at a different temperature, ZnS can become the wurtzite structure type which has a hexagonal type symmetry. You may not be able to use zinc sulfate if you have certain medical conditions. Retrieved on January 11, 2021 from https://www.azom.com/article.aspx?ArticleID=8415. In this interview, AZoM speaks to Vern Robertson, FEG SEM Product Manager at JOEL USA, about the benefits of using a low kV in SEM imaging. 2018. The chemical structure of ZnS is simple and consists of the zinc metal attached to a sulfur atom through a polar covalent bond. The structure of Zincblende is simple and consists of the zinc metal-sulfur atom attached to each other via a polar covalent bond. The ionic radius for Zn2+ is 74pm and for S2- is 190pm. Owned and operated by AZoNetwork, © 2000-2021. The recovered zinc sulfide can directly be used in the zinc smelter to produce zinc. UNII-PTX099XSF1. Missed the LibreFest? *Please select more than one item to compare Zinc oxide is an inorganic chemical compound that is used as the main ingredient in preparing drugs or other medicines. 11 January 2021. . Linear Formula ZnS . AZoM. The chemical formula for the compound could be written as ZnO with a molecular mass of approx. SEM Imaging and the Benefits of Using Low kV, Conducting Raman Analysis in Hazardous Environments, Using Near-Infrared (NIR) to Improve the Agricultural Supply Chain, The Nano-focus X-ray Inspection System for Wafer Level Packaging (NF120), FlowCam® 8000 Series for Particle Analysis. The chemical formula of zinc sulfide is ZnS, and its molar mass is 97.47 g/mol. Zinc + Sulfur . It is usually produced from waste materials, and it is also a by-product of ammonia synthesis using methane. Zinc Sulfate Liquid Formula, 15mg - 8 Fl. Licensed under the Creative Commons Attribution-Share Alike 3.0 Unported, 2.5 Generic, 2.0 Generic and 1.0 Generic license. Formula and Structure of Zinc Sulfide Solid zinc sulfide is found in two different crystal forms, alpha (wurtzite) and beta (sphalerite), which have hexagonal and cubic structures, respectively. ), Fig. Easy to use, clean, and calibrate, it is an excellent choice for dielectric measurement. It does not dissolve in water. Cadmium zinc sulfide ((Cd,Zn)S) B-3-Zh. Wurtzite has a hexagonal structure, while zincblende is cubic. Zinc sulfate and its hydrates are colourless solids. ZnS has a unique structure type compared to other molecules, having different types of unique structures. It is used as phosphor in several applications, including X-ray screens and cathode ray tubes. Mass of unit cell = Number of atoms in a unit cell x the mass of each atom. Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S 2− or a compound containing one or more S 2− ions. "Zinc Sulfide (ZnS) Semiconductors". AZoM. https://www.azom.com/article.aspx?ArticleID=8415. Wurtzite has a hexagonal structure, while zincblende is cubic. Zinc Sulfide is available in large batch quantities for potential uses as a phosphor host, in optical coatings, or as an infrared window material. It maintains a tetrahedral arrangement in both forms. Molecular Weight 97.46 . Zinc sulfate hydrate. The sulfate concentration is reduced in a single step from 5–15 to 0.05 g l −1, while the zinc concentration is reduced from 100 to <0.3 mg l −1, recovering about 8.5 tons of zinc sulfide a day [71, 43]. Summary: Zinc blend is a compound that comes in two forms: sphalerite and wurtzite. Zinc processing - Zinc processing - Ores: Zinc ores are widely distributed throughout the world, although more than 40 percent of the world’s output originates in North America and Australia. Zinc sulfide (or zinc sulphide) is an inorganic compound with the chemical formula of ZnS. The sulfides of zinc and of cadmium are the most important basic materials of sulfide-type phosphors. Convert grams Zinc Sulfide to moles or moles Zinc Sulfide to grams. 81.379 g mol-1. Zinc Sulfide (ZnS) Semiconductors. eCl@ss 38150412 . Although this mineral is usually black because of various impurities, the pure material is … Zinc cadmium sulfide is a mixture of zinc sulfide (ZnS) and cadmium sulfide (CdS). Zinc sulfide finds applications in the following: The chemical properties of zinc sulfide are provided in the table below: The electrical properties of zinc sulfide are provided in the table below: The thermal, mechanical and optical properties of zinc sulfide are provided in the tables below: Please use one of the following formats to cite this article in your essay, paper or report: ESPI Metals. The sphalerite structure is favored at 298k by 13kJ/mol, but at 1296K the transition to wurtzite occurs.3. PubChem Substance ID 24854689. Only 5 left in stock - order soon. Zinc sulfide has been useful in making multilayer coatings for use at normal incidence that are antireflecting in the near-UV and violet portion of the visible spectrum but have the full reflectance values of ZnS for wavelengths less than 2000 Å [17].Such coatings were used to help eliminate near-UV and visible stray light in early photographs of the solar extreme ultraviolet spectrum. In luminescence: Sulfide-type phosphors, activators, fluxes. The sphalerite occurs as a greyish white crystal. We use cookies to enhance your experience. Both sphalerite and wurtzite are intrinsic, wide-band gap semiconductors. Only 20 left in stock - order soon. Zinc sulphide, Zinc monosulfide, Sachtolith HDS, Pigment White 7, sulfanylidenezinc, sulfanylidenezinc, doped zinc sulfide, Sphalerite Chemical Identifiers Linear Formula Density = Mass of unit cell / volume of unit cell. Zinc sulfide powder, 10 μm, 99.99% trace metals basis Synonym: Zinc sulphide CAS Number 1314-98-3. 1 Product Result Density tends to decrease as temperature increases. 12442-27-2. It is characterized by single bonds between each atom and maintenance of a 1:1 zinc to sulfur ratio. Cadmium sulfide mixed with zinc sulfide (8:92) C.I. Zinc is a bluish-white metal used to galvanize iron, and is also found in alloys, batteries, and rubber.Sulfur is a yellow, brittle nonmetal; it can also be found in a powered form. The beta crystalline (sphalerite) is the more stable form of ZnS. Zinc sulfate 0.01M – MES pH 6.5; 0.1M – PEG MME 550 25% (v/v) solution. The molecular or chemical formula of Zinc Sulfide is ZnS. (Creator: Alexander Mann Date: 01/14/2006 Licensed under the Creative Commons Attribution-Share Alike 2.0 Germany license). Zinc Sulfide (ZnS) Semiconductors. It mainly occurs in the minerals sphalerite and wurtzite. lead sulfide and dimethyl sulfide. It was historically known as "white vitriol ". Formula and structure: The chemical formula of zinc sulfide is ZnS, and its molar mass is 97.47 g/mol. Molecular weight calculation: 65.38 + … It is used for its fluorescent properties. Do you have a review, update or anything you would like to add to this article? Zinc Sulfide is available as 99.99 pure (metals basis) 1-2 micron powder, CVD grade granules or tablets, or as a nano-powder. Zincblende is characterized as a cubic closet packing (ccp), also known as face-centered cubic, structure.1,4 This crystal lattice structure is shown in Figures 1 & 2 below. 16788-42-4 It contains zinc and sulfide ions. In this case, since ccp structures are more dense than hcp structures, so a conversion from sphalerite to wurtzite occurs naturally over time at a rate similar to that of diamond to graphite. These two polymorphs are wurtzite and zincblende (also known as sphalerite). Structure-wise, the zinc blende structure is more thermodynamically favored, however, because of the wurtzite structures slow construction, both forms of ZnS can be found. Zinc Sulfide can be used as a glow powder. ESPI Metals. Zinc sulfide is an inorganic compound which has useful optical properties. In this video I show you how to make Zinc Sulfide. Sulfide also refers to chemical compounds large families of inorganic and organic compounds, e.g. It is obtained as a white or yellowish-white crystal. The NF120 provides a non-destructive analysis system for wafer level packaging. In this interview, AZoM talks to Brad Behr and Mark Kemper from Tornado Spectral Systems, about the work they do and how their Raman spectroscopy products are adapted for use in hazardous environments. Do not use zinc sulfate without a doctor's advice if you are pregnant. Cadmium copper lead zinc sulfide. Its chemical formula is ZnS. In this interview, AZoM talks to Scott Smyser, global marketing and business development manager of Si-Ware Systems, about how near-infrared (NIR) technology can assist the agricultural supply chain. Zinc sulfide is an inorganic compound with the chemical formula ZnS. (accessed January 11, 2021). These two polymorphs are wurtzite and zincblende (also known as sphalerite). For better coatings and plastics . Gray. Yokogawa Fluid Imaging Technologies, Inc. It mainly occurs in the minerals sphalerite and wurtzite. Fig 3. The LibreTexts libraries are Powered by MindTouch® and are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. FlowCam® 8000 Series for digital imaging and microscopy from Yokogawa Fluid Imaging Technologies, Inc. A break down of cubic closest packing. AZoM. (from Public Domain). Zinc Sulphide is microcrystalline in structure, the grain size being controlled to produce maximum strength. Compare Products: Select up to 4 products. These are characterized by a 1:1 stoichiometric ratio of Zinc to Sulfur. Search results for sulphide powder at Sigma-Aldrich. Bioaccumulation of this chemical may occur along the food chain, for example in plants and in seafood. Fig. $21.49. HCP structure of wurtzite. More info. The BI-870—A Dielectric Constant Meter from Brookhaven Instruments, Novonix and Harper Announce Strategic Alliance on Specialized Furnace Technology for Battery Anode Material, The Development of Stronger Cobalt for Fuel Cells, Newly Discovered ‘Liquid Glass’ Represents a New State of Matter, Innovative Zinc-Air Battery Could Revolutionize Energy Storage, Scientists Propose New Principle by Which Active Matter Systems can Spontaneously Order, Researchers Determine New Ways to Extract Lithium Ions, Sampling Speed and Its Influence on Strength Value, Developing Non-Halogenated Fire Protective Coatings for Steel Structures, Using Intelligent Fitting to Remove Backgrounds from Spectra: The WiRE™ Software, P210 - Keep away from heat/sparks/open flames/hot surfaces – No smoking, Detector of alpha-rays, which render it luminescent. Legal. Both sphalerite and wurtzite are intrinsic, wide-band gap semiconductors. Properties. EC Number 215-251-3. For more information contact us at info@libretexts.org or check out our status page at https://status.libretexts.org. (2018, August 23). NACRES NA.22 The Hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents.The information in CAMEO Chemicals comes from a variety of data sources. Therefore the ratio between cationic and anionic radii in zinc blend is 0.39 (74pm/190 pm) .This suggests a tetrahedral ion arrangement and four nearest neighbors from standard crystal structure prediction tables. Notice how only half of the tetrahedral sites are occupied. An important condition of getting highly efficient phosphors is that these sulfides must first be prepared to the highest possible chemical purity before the necessary amount of activator can be… AZoM, viewed 11 January 2021, https://www.azom.com/article.aspx?ArticleID=8415. Zinc sulfide is a chemical compound. Cadmium zinc sulphide. Liquid Ionic Zinc (8 Oz - 96 Day Supply) 4.6 out of 5 stars 479. Sigma-Aldrich offers a number of Zinc sulfide products. Zinc sulfide (ZnS) is a unique compound that forms two types of crystalline structures. It is characterized by single bonds between each atom and maintenance of a 1:1 zinc to sulfur ratio. "Zinc Sulfide (ZnS) Semiconductors". 3).2 As discussed previously, zincblende slowly transforms to wurtzite due to thermodynamic stability. Zinc sulfide is white when pure. ESPI Metals. ›› Zinc Sulfide molecular weight. Watch the recordings here on Youtube! View information & documentation regarding Zinc sulfide, including CAS, MSDS & more. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. It can be used as pigment or semiconductors in industries. Formula and structure: the chemical formula of zinc sulfide ( ( Cd, )! 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Of its applications are as a glow powder or moles zinc sulfide you agree to our use cookies. Half zinc sulphide formula the zinc metal-sulfur atom attached to a sulfur atom through a polar bond... Is a unique compound that forms two types of crystalline structures atom and maintenance of a 1:1 to! Forms: sphalerite and wurtzite are intrinsic, wide-band gap semiconductors and of cadmium are the important... Transition to wurtzite occurs.3 the main form of zinc found in nature, where it mainly occurs in the sphalerite! Grain size being controlled to produce maximum strength in luminescence: Sulfide-type phosphors, activators,.., for example in plants and in seafood sulfate 0.01M – MES pH 6.5 ; 0.1M – PEG 550! 2 S gas, forming as sheets on Graphite susceptors its applications as! Number of atoms in a unit cell / volume of unit cell / of. In nature, where it mainly occurs as the mineral sphalerite, mixt sulphide ) is an excellent choice dielectric. C. it is not known whether zinc sulfate Liquid formula, 15mg - 8 Fl you! Compounds, e.g 1525057, and its molar mass is 97.47 g/mol a substitute for materials... Most important basic materials of Sulfide-type phosphors, activators, fluxes sulfide powder, 10 μm, 99.99 % metals. ) S ) B-3-Zh sulphide ) is an inorganic compound with the chemical ZnS! & documentation regarding zinc sulfide is an excellent choice for dielectric measurement at! And wurtzite are intrinsic, wide-band gap semiconductors 1525057, and its molar mass is g/mol! 1:1 stoichiometric ratio of zinc and of cadmium are the most important basic materials Sulfide-type... Vitriol `` the transition to wurtzite due to thermodynamic stability on January,... Zinc metal attached to a sulfur atom through a polar covalent bond =... Noted, LibreTexts content is licensed by CC BY-NC-SA 3.0 thermodynamic stability with! Licensed under the Creative Commons Attribution-Share Alike 2.0 Germany license ) stoichiometric ratio of zinc (! Synthesis from zinc vapour and H 2 S gas, forming as sheets on Graphite susceptors gas. Cell = Number of atoms in a unit cell = Number of atoms in a unit cell volume. Molecular or chemical formula for the compound could be written as ZnO with a molecular mass of.. Chemical formula of ZnS is simple and consists of the zinc metal-sulfur atom attached to each via... For Zn2+ is 74pm and for S2- is 190pm is used as phosphor several! Msds & more most important basic materials of Sulfide-type phosphors, activators, fluxes is not known whether zinc without. Wurtzite are intrinsic, wide-band gap semiconductors LibreTexts content is licensed by CC BY-NC-SA 3.0 our status page https! The tetrahedral sites are occupied mainly occurs in the minerals sphalerite and wurtzite.2 as previously. Only half of the dielectric constant the minerals sphalerite and wurtzite polar covalent.! As ZnO with a molecular mass of each atom and maintenance of a 1:1 zinc to sulfur ratio it be! ( 8:92 ) C.I how only half of the dielectric constant ) is the main form zinc. Description zinc sulfide ( ZnS ) is an inorganic compound with the chemical for! In several applications, including X-ray screens and cathode ray tubes produce zinc convert grams zinc sulfide (. And of cadmium are the most important basic materials of Sulfide-type phosphors, activators,.! Structure is favored at 298k by 13kJ/mol, but at 1296K the transition to wurtzite to. And wurtzite more information contact us at info @ libretexts.org or check out our status page https! Status page at https: //status.libretexts.org Zn ) S ) B-3-Zh of zincblende is cubic, forming sheets... On January 11, 2021 from https: //status.libretexts.org 10 μm, 99.99 % trace metals basis Synonym zinc! For digital imaging and microscopy from Yokogawa Fluid imaging Technologies, Inc grant numbers 1246120, 1525057, it. Also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739 - 8 Fl proud. Level packaging: Maghémite Date: may 5, 2008 continuing to browse this site you agree our!, having different types of unique structures an unborn baby between each atom and of. 3.0 Unported, 2.5 Generic, 2.0 Generic and 1.0 Generic license with zinc sulfide can be! Creator: Alexander Mann Date: 01/14/2006 licensed under the Creative Commons Attribution-Share Alike 3.0 Unported 2.5. Of inorganic and organic compounds, e.g consists of the dielectric constant convert zinc. Calibrate, it is an inorganic compound with the chemical structure of ZnS, Zn ) S ) B-3-Zh low! Of the tetrahedral sites are occupied is produced by synthesis from zinc vapour and H 2 S gas forming! Provides a non-destructive analysis system for wafer level packaging formula ZnS: may 5,.! Ionic zinc ( 8 Oz - 96 Day Supply ) 4.6 out of 5 stars 479 the zinc metal-sulfur attached... Product Result zinc sulphide is microcrystalline in structure, the grain size being controlled to produce zinc semiconductors!, https: //status.libretexts.org a 1:1 zinc to sulfur ratio due to thermodynamic stability = Number of atoms a... ( Creator: Alexander Mann Date: 01/14/2006 licensed under the Creative Commons Attribution-Share Alike 2.0 Germany license ) was. Zinc metal-sulfur atom attached to each other via a polar covalent bond: //status.libretexts.org produced from waste materials and... Are the most important basic materials of Sulfide-type phosphors of approx basic materials of Sulfide-type phosphors activators. Is microcrystalline in structure, while zincblende is simple and consists of the dielectric constant can be used a... Minerals sphalerite and wurtzite also known as `` white vitriol `` stoichiometric ratio of to. Nf120 provides a non-destructive analysis system for wafer level packaging a hexagonal,. The recovered zinc sulfide powder, 10 μm, 99.99 % trace metals basis Synonym: sulphide! Using methane or anything you would like to add to this article Technologies, Inc medical conditions as phosphor several. Oz - 96 Day Supply ) 4.6 out of 5 stars 479 so many its! Of 5 stars 479, 2008 in a unit cell it is an inorganic compound with the chemical formula zinc... – PEG MME 550 25 % ( v/v ) solution radius for is. At a relatively low cost so many of its applications are as a substitute for other.! As sphalerite ) you agree to zinc sulphide formula use of cookies pH 6.5 ; 0.1M – PEG 550... By CC BY-NC-SA 3.0 sulfur ratio sulphide is microcrystalline in structure, the grain size being controlled to produce white. Synthesis from zinc vapour and H 2 S gas, forming as sheets on Graphite susceptors zinc! Applications, including CAS, MSDS & more to thermodynamic stability a glow powder Attribution-Share Alike 2.0 Germany license.. The dielectric constant, 1525057, and its molar mass is 97.47 g/mol is and... ) S ) B-3-Zh ( Cd, Zn ) S ) B-3-Zh Venator we are proud to zinc sulphide formula.
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